Intramolecular Borylene Transfer Leading to the Formation of a μ3‑BC2 Ring on a Triruthenium Cluster
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资源简介：
Photoirradiation of a triruthenium alkyne complex containing a μ3-borylene ligand, {Cp*Ru(μ-H)}3(μ3-η2(∥)-PhCCH)(μ3-BH) (Cp* = η5-C5Me5), was examined; whereas a perpendicularly coordinated alkyne complex was obtained by the irradiation with UV light (313 nm), a trimetallic complex containing a three-membered μ3-η3-BC2 ring was preferentially formed as a result of intramolecular borylene transfer by the irradiation with visible light (436 nm).
创建时间：
2016-02-19
