Enantioselective Synthesis of 2,3-Disubstituted Indanones via Pd-Catalyzed Intramolecular Asymmetric Allylic Alkylation of Ketones
收藏Figshare2016-02-18 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Enantioselective_Synthesis_of_2_3_Disubstituted_Indanones_via_Pd_Catalyzed_Intramolecular_Asymmetric_Allylic_Alkylation_of_Ketones/2346337
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A Pd-catalyzed intramolecular asymmetric allylic alkylation (AAA) reaction with “hard” carbanions has been developed for the first time, affording 2,3-disubstituted indanones with high diastereo- and enantioselectivities. The transformation of these products into other core structures of natural products has been demonstrated.
创建时间:
2016-02-18



