Platinum-Mediated Dinitrogen Liberation from 2‑Picolyl Azide through a Putative PtN Double Bond Containing Intermediate
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资源简介：
2-Picolyl azide reacts with cis-[PtCl2(DMSO)2] to form the diimino complex [PtIICl2{NHC(H)Py}] with subsequent dinitrogen liberation. The formation of the latter complex is scrutinized in a combined experimental and theoretical analysis. We establish in silico that the transformation involves a highly reactive intermediate containing a PtN double bond formed after the extrusion of N2 from the azide functionality. The prerequisites for N2 liberation and for the stabilization of the nitrene-related intermediate are analyzed in detail.
创建时间：
2016-02-19
