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Regioselective Carbon–Carbon Bond Cleavage in the Oxidation of Cyclopropenylcarbinols

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NIAID Data Ecosystem2026-03-07 收录
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The strained double bond of cyclopropenylcarbinols undergoes a facile oxidation reaction to lead to unsaturated carbonyl derivatives. The distribution of the formed products depends on the relative stability of carbon-centered radical species, and the Sharpless kinetic resolution leads to enantiomerically pure Baylis–Hillman enal adducts.

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2016-02-23
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