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An Effective Pd-Catalyzed Regioselective Hydroformylation of Olefins with Formic Acid

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https://figshare.com/articles/dataset/An_Effective_Pd-Catalyzed_Regioselective_Hydroformylation_of_Olefins_with_Formic_Acid/4212612
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An effective palladium-catalyzed regioselective hydroformylation of olefins with formic acid is described. The ligand plays a crucial role in directing the reaction pathway. Linear aldehydes can be obtained in up to 93% yield with >20:1 regioselectivity using 1,3-bis­(diphenylphosphino)­propane (dppp) as the ligand. The reaction process is operationally simple and requires no syngas.
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2016-11-10
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