Lithium Dimethyl(amido)zinc Complexes: Contrasting Zincate (Amido = TMP) and Inverse Zincate (Amido = HMDS) Structures on Addition of TMEDA
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https://figshare.com/articles/dataset/Lithium_Dimethyl_amido_zinc_Complexes_Contrasting_Zincate_Amido_TMP_and_Inverse_Zincate_Amido_HMDS_Structures_on_Addition_of_TMEDA/3073303
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资源简介：
Introducing TMEDA to the lithium dimethyl(amido)zincates “LiZn(NR2)Me2” leads to a discrete ion-contacted
zincate with TMEDA bound to lithium in the case of NR2 =
TMP but to a novel “inverse zincate” with TMEDA bound to
zinc in the case of NR2 = HMDS, where unexpectedly Me2Zn(TMEDA) functions as a η1,μ ligand to dimeric (LiHMDS)2
molecules to afford a zigzag chain polymer.
创建时间：
2016-03-01
