Palladium-Catalyzed Asymmetric Dearomatization of Naphthalene Derivatives

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https://figshare.com/articles/dataset/Palladium_Catalyzed_Asymmetric_Dearomatization_of_Naphthalene_Derivatives/2855932 数据链接链接失效反馈

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资源简介：

Palladium-Catalyzed Asymmetric Dearomatization of Naphthalene Derivatives

创建时间：

2016-02-26

Tertiary Amine-Triggered Cascade S N 2/Cycloaddition: An Efficient Construction of Complex Azaheterocycles under Mild Conditions

有机合成方法

氮杂环构建

In this paper, an amine-triggered cascade SN2/cycloaddtion sequence between 2-(acetoxymethyl)buta-2,3-dienoate 1 and various π-system functionalized tosylamides 3 has been reported, which provides a f

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Synthesis of (±)-Idarubicinone via Global Functionalization of Tetracene

药物合成

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Anthracyclines are archetypal representatives of the tetracyclic type II polyketide natural products that are widely used in cancer chemotherapy. Although the synthesis of this class of compounds has

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Anti-Selective Organocatalytic Michael Addition between Phenylacetaldehyde and Nitrostyrene

不对称催化

迈克尔加成反应机理

Using the reaction between phenylacetaldehyde and nitrostyrene catalyzed by pyrrolidine as a simple model, we have studied the diastereochemical outcome of the organocatalytic Michael reactions betwee

Figshare2016-08-29 更新00

Facile Synthesis of β-Tribromomethyl and Dibromomethylenated Nitroalkanes via Conjugate Addition of Bromoform to Nitroalkenes

有机合成方法

硝基化合物修饰

Addition of bromoform to conjugated nitroalkenes in the presence of Mg provided β-tribromomethyl nitroalkanes in good to excellent yields and diastereoselectivity. These novel Michael adducts, formed

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Asymmetric Synthesis of Heterobimetallic Planar Chiral Ferrocene Pallada-/Platinacycles and Their Application to Enantioselective Aza-Claisen Rearrangements

不对称催化

Aza-Claisen重排

Ligand exchange reactions are usually slower for Pt(II) in comparison to Pd(II) centers. Mainly for that reason Pt(II) catalysts have often shown a reduced catalytic activity as compared to their P

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Palladium-Catalyzed Asymmetric Dearomatization of Naphthalene Derivatives

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