Functionalized Oxepines via Fragmentation of Highly Strained Epoxides
收藏NIAID Data Ecosystem2026-03-06 收录
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Epoxidation of highly strained cyclobutenes followed by thermal rearrangement provides a new entry into oxepine-containing bicyclo[5.3.0] ring systems. In contrast to the rearrangement of the corresponding cyclopropanated systems, the strained epoxides in this study are believed to fragment through two competing pathways leading to a mixture of diastereomeric 5-7 ring systems.
创建时间:
2016-02-29



