Octahedral Ruthenium Complex with Exclusive Metal-Centered Chirality for Highly Effective Asymmetric Catalysis
收藏Figshare2017-03-20 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Octahedral_Ruthenium_Complex_with_Exclusive_Metal-Centered_Chirality_for_Highly_Effective_Asymmetric_Catalysis/4765834
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资源简介：
A novel ruthenium catalyst is introduced which contains solely achiral ligands and acquires its chirality entirely from octahedral centrochirality. The configurationally stable catalyst is demonstrated to catalyze the alkynylation of trifluoromethyl ketones with very high enantioselectivity (up to >99% ee) at low catalyst loadings (down to 0.2 mol%).
创建时间：
2017-03-20
