Straightforward Synthesis and Structure of a New Starting Material for Niobium Cluster Phases: [Nb<sub>6</sub>Cl<sup>i</sup><sub>12</sub>(CH<sub>3</sub>OH)<sup>a</sup><sub>4</sub>Cl<sup>a</sup><sub>2</sub>]·6CH<sub>3</sub>OH
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A new, fast, and straightforward synthetic route for the new cluster compound [Nb6Cli12(CH3OH)a4Cla2]·6CH3OH, taking advantage of the special solubility properties of tetracyanoborate salts has been established, and the single-crystal X-ray structure of this compound, which is a promising starting material for new cluster phases, has been determined.
创建时间:
2006-10-30



