Self-Assembly of [M<sub>13</sub>Ni<sub>8</sub>S<sub>8</sub>(edt)<sub>14</sub>]<sup>2–</sup> (M = Cd, Zn): A New Type of Henicosnuclear Heterometallic Clusters Based on Two Primary Building Units
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A new type of henicosnuclear heterometallic clusters [Cd13Ni8S8(edt)14](Et3NH)2·2H2O (edt = 1,2-ethanedithiol) (1) and [Zn13Ni8S8(edt)14](H2bpp) (bpp = 1,3-di(4-pyridyl)propane) (2) have been synthesized by solvothermal reaction. The MS4 (M = Cd, Zn) tetrahedron and the NiS4 square plane construct the two unprecedented chalcogenide-based heterometallic clusters as two primary building units.
创建时间:
2016-02-20



