A Super-Reduced Diferrous [2Fe–2S] Cluster
收藏NIAID Data Ecosystem2026-03-07 收录
下载链接：
https://figshare.com/articles/dataset/A_Super_Reduced_Diferrous_2Fe_2S_Cluster/2446303
下载链接
链接失效反馈官方服务：
资源简介：
A biomimetic [2Fe–2S] cluster has been isolated
in the fully
reduced diferrous form and characterized by X-ray diffraction. This
completes a consistent series of synthetic analogues of protein-bound
[2Fe–2S]z redox centers (z = 2+, 1+, 0) with identical capping ligands. 57Fe Mössbauer data of the extremely oxidation-sensitive complex
compare well with those of the very few reports of all-ferrous ferredoxins
and Rieske centers; they confirm the ST = 0 ground state and establish a lower limit for the exchange coupling,
−J ≥ 30 cm–1.
创建时间：
2013-02-06
