An N-Heterocyclic Carbene-Catalyzed [8 + 3] Annulation of Tropone and Enals via Homoenolate
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https://figshare.com/articles/dataset/An_N_Heterocyclic_Carbene_Catalyzed_8_3_Annulation_of_Tropone_and_Enals_via_Homoenolate/3048721
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资源简介:
A novel protocol for the annulation of tropone to enals
involving nucleophilic heterocyclic carbene (NHC) catalyzed
homoenolate formation has been developed. Interestingly,
the reaction led to bicyclic δ-lactones instead of the expected
γ-spirolactones, presumably by the uncommon [8 + 3]
annulation pathway. The strategy works well with a variety
of enals.
创建时间:
2016-02-29



