Palladium-Catalyzed Enantioselective C–H Activation of Aliphatic Amines Using Chiral Anionic BINOL-Phosphoric Acid Ligands
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https://figshare.com/articles/dataset/Palladium-Catalyzed_Enantioselective_C_H_Activation_of_Aliphatic_Amines_Using_Chiral_Anionic_BINOL-Phosphoric_Acid_Ligands/4560778
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资源简介：
The
design of an enantioselective Pd(II)-catalyzed C–H amination
reaction is described. The use of a chiral BINOL phosphoric acid ligand
enables the conversion of readily available amines into synthetically
valuable aziridines in high enantiomeric ratios. The aziridines can
be derivatized to afford a range of chiral amine building blocks incorporating
motifs readily encountered in pharmaceutically relevant molecules.
创建时间：
2017-01-18
