Polyoxomolybdate-Supported Bismuth Trihalides [Mo8O26(BiX3)2]4– (X = Cl, Br, I): Syntheses and Study of Polymorphism
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Octamolybdate complexes TBA4[Mo8O26(BiX3)2] (TBA = n-tetrabutylammonium, X = Cl (1), Br (2), I (3)) were obtained by straightforward syntheses from TBA4[Mo8O26] and corresponding Bi(III) halides in MeCN. All compounds were structurally characterized; in all cases, {BiX3} fragments are coordinated by two oxygen atoms of polyoxometalate core. Occurring polymorphism is also discussed.
创建时间：
2016-02-17
