Synthesis and Structure of Group IV Distanna[2]metallocenophanes
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https://figshare.com/articles/dataset/Synthesis_and_Structure_of_Group_IV_Distanna_2_metallocenophanes/2333350
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资源简介：
1,2-Dichloro-1,1,2,2-tetra-tert-butyldistannane
reacts with 2 equiv of sodium cyclopentadienide to give a bis(cyclopentadienyl)distannane.
Subsequent dilithiation with lithium diisopropylamide and reactions
with suitable metal halides yield [(C5H4SntBu2)2MCl2] (M = Ti, Zr,
Hf). The group 4 ansa-metallocenes have all been
fully characterized by means of multinuclear NMR spectroscopy, elemental
analysis, and X-ray diffraction.
创建时间：
2016-02-18
