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Na4MgM2Se6 (M = Si, Ge): The First Noncentrosymmetric Compounds with Special Ethane-like [M2Se6]6– Units Exhibiting Large Laser-Damage Thresholds

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Figshare2016-02-12 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Na_sub_4_sub_MgM_sub_2_sub_Se_sub_6_sub_M_Si_Ge_The_First_Noncentrosymmetric_Compounds_with_Special_Ethane_like_M_sub_2_sub_Se_sub_6_sub_sup_6_sup_Units_Exhibiting_Large_Laser_Damage_Thresholds/2116192
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Two new noncentrosymmetric compounds, Na4MgM2Se6 (I, M = Si; II, M = Ge), that contain special ethane-like [M2Se6]6– units were reported for the first time. Remarkably, they exhibit high laser-damage thresholds [9 (I) and 7 (II) × benchmark AgGaS2] and moderate second-harmonic-generation responses with type I phase matching.
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2016-02-12
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