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<i>all-anti</i>-Pentasilane: Conformation Control of Oligosilanes Based on the Bis(tetramethylene)-Tethered Trisilane Unit

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NIAID Data Ecosystem2026-03-06 收录
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A bicyclic trisilane unit affords all-anti peralkylated pentasilane with dihedral angles ω > 178°. Its UV and MCD spectra as well as the X-ray crystallography of a related compound demonstrate the highly σ-conjugated system due to the rigidity of the silicon chain conformation.

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2016-05-06
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