Electrophilic nitration of alkanes with nitronium hexafluorophosphate
收藏PubMed Central1997-10-28 更新2026-05-02 收录
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https://pmc.ncbi.nlm.nih.gov/articles/PMC23573/
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资源简介：
Nitration of alkanes such as methane, ethane, propane, n-butane, isobutane, neopentane, and cyclohexane was carried out with nitronium hexafluorophosphate in methylene chloride or nitroethane solution. Nitration of methane, albeit in poor yield, required protolytic activation of the nitronium ion. The results indicate direct electrophilic insertion of NO(2)(+) into C[bond ]H and C[bond ]C σ-bonds.
提供机构：
National Academy of Sciences
创建时间：
1997-10-28
