Toward Higher Nuclearity: Tetranuclear Cobalt(II) Metallogrid Exhibiting Spin Crossover
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https://figshare.com/articles/dataset/Toward_Higher_Nuclearity_Tetranuclear_Cobalt_II_Metallogrid_Exhibiting_Spin_Crossover/2318920
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资源简介:
Supramolecular
strategy was employed to achieve the highest nuclearity Co(II) cluster
exhibiting spin-crossover (SCO) behavior. Magnetic susceptibility
characterization of the Co4II complex shows
that two different spin-transition processes occur. The SCO behavior
is directed by the partially deprotonated polydentate ligand, which
favors the structural distortion required by the spin transition.
创建时间:
2014-03-03



