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Highly Selective, Efficient Deoxygenative Hydrogenation of Amides Catalyzed by a Manganese Pincer Complex via Metal–Ligand Cooperation

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NIAID Data Ecosystem2026-03-10 收录
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https://figshare.com/articles/dataset/Highly_Selective_Efficient_Deoxygenative_Hydrogenation_of_Amides_Catalyzed_by_a_Manganese_Pincer_Complex_via_Metal_Ligand_Cooperation/6890624
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资源简介:
Deoxygenative hydrogenation of amides to amines homogeneously catalyzed by a complex of an Earth-abundant metal is presented. This manganese-catalyzed reaction features high efficiency and selectivity. A plausible reaction mechanism, involving metal–ligand cooperation of the manganese pincer complex, is proposed based on NMR studies and relevant stoichiometric reactions.
创建时间:
2019-04-04
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