Catalytic Enantioselective O‑Nitrosocarbonyl Aldol Reaction of β‑Dicarbonyl Compounds
收藏Figshare2016-02-20 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Catalytic_Enantioselective_i_O_i_Nitrosocarbonyl_Aldol_Reaction_of_Dicarbonyl_Compounds/2469100
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资源简介：
The first example of a Cu-catalyzed asymmetric O-nitrosocarbonyl aldol reaction is described. This novel protocol allows convenient access to highly enantioenriched α-hydroxy-β-ketoesters including the antibacterial natural product kjellmanianone (up to 99% ee). MnO2 was introduced as a mild efficient oxidant for the in situ generation of nitrosocarbonyl species from hydroxamic acid derivatives.
创建时间：
2016-02-20
