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Axially Chiral NHC−Pd(II) Complexes in the Oxidative Kinetic Resolution of Secondary Alcohols Using Molecular Oxygen as a Terminal Oxidant

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https://figshare.com/articles/dataset/Axially_Chiral_NHC_Pd_II_Complexes_in_the_Oxidative_Kinetic_Resolution_of_Secondary_Alcohols_Using_Molecular_Oxygen_as_a_Terminal_Oxidant/3021364
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资源简介:
Axially chiral N-heterocyclic carbene (NHC) Pd(II) complexes were prepared from optically active 1,1‘-binaphthalenyl-2,2‘-diamine (BINAM) and H8-BINAM and applied in the oxidative kinetic resolution of secondary alcohols using molecular oxygen as a terminal oxidant. The corresponding sec-alcohols can be obtained in good yields with moderate to good enantioselectivities.
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2016-02-29
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