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Self-Assembly of [M13Ni8S8(edt)14]2– (M = Cd, Zn): A New Type of Henicosnuclear Heterometallic Clusters Based on Two Primary Building Units

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Figshare2016-02-20 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Self_Assembly_of_M_sub_13_sub_Ni_sub_8_sub_S_sub_8_sub_edt_sub_14_sub_sup_2_sup_M_Cd_Zn_A_New_Type_of_Henicosnuclear_Heterometallic_Clusters_Based_on_Two_Primary_Building_Units/2490463
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A new type of henicosnuclear heterometallic clusters [Cd13Ni8S8(edt)14]­(Et3NH)2·2H2O (edt = 1,2-ethanedithiol) (1) and [Zn13Ni8S8(edt)14]­(H2bpp) (bpp = 1,3-di­(4-pyridyl)­propane) (2) have been synthesized by solvothermal reaction. The MS4 (M = Cd, Zn) tetrahedron and the NiS4 square plane construct the two unprecedented chalcogenide-based heterometallic clusters as two primary building units.
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2016-02-20
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