Unusual Transformation of the Diarylmethanol Derivative into an Unknown 1,2,3,6,7,10-Hexahydroxylated Anthracene System
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下载链接:
https://figshare.com/articles/dataset/Unusual_Transformation_of_the_Diarylmethanol_Derivative_into_an_Unknown_1_2_3_6_7_10_Hexahydroxylated_Anthracene_System/3230137
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资源简介:
10-Benzyloxy-1,2,3-trimethoxy-6,7-(methylene-1,3-dioxy)anthracene
as a potential material for molecular electronics was synthesized from the O-benzyl-protected diarylmethanol derivative containing the 1,3-dioxyethylene acetal function via a
one-pot procedure under acidic conditions (1 N HCl,
methanol, 60 h) in 60% yield. The replacement of methanol
for benzene resulted in hydrolysis of the acetal function in
96% yield.
创建时间:
2016-05-05



