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Axle length- and solvent-controlled construction of (pseudo)[1]rotaxanes from mono-thiourea-functionalised pillar[5]arene derivatives

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Taylor & Francis Group2023-05-31 更新2026-04-16 收录
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https://tandf.figshare.com/articles/dataset/Axle_length-_and_solvent-controlled_construction_of_pseudo_1_rotaxanes_from_mono-thiourea-functionalised_pillar_5_arene_derivatives/4622578/1
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资源简介:
A series of thiourea-functionalised pillar[5]arene derivatives <b>3</b><sup><b>n</b></sup><b>m</b> were constructed from a series of mono-amide-functionalised pillar[5]arenes <b>2</b><sup><b>n</b></sup>. The formation of their free forms or (pseudo)[1]rotaxane structures were controlled by their axle lengths or solvents, which were investigated by <sup>1</sup>H NMR spectroscopy. Some of (pseudo)[1]rotaxane structures were also supported by their single-crystal structures.
提供机构:
Han, Ying; Lin, Chen; Yan, Chao-Guo; Sun, Jing; Wang, Leyong; Lu, Yiheng; Huo, Gui-Fei
创建时间:
2017-02-06
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