Materials Data on AgCNO by Materials Project

AgNCO crystallizes in the orthorhombic Pmmn space group. The structure is two-dimensional and consists of two AgNCO sheets oriented in the (0, 0, 1) direction. Ag1+ is bonded in a distorted rectangular see-saw-like geometry to two equivalent C4+ and two equivalent O2- atoms. Both Ag–C bond lengths are 2.21 Å. Both Ag–O bond lengths are 2.57 Å. C4+ is bonded in a distorted trigonal planar geometry to two equivalent Ag1+ and one N3- atom. The C–N bond length is 1.19 Å. N3- is bonded in a linear geometry to one C4+ and one O2- atom. The N–O bond length is 1.25 Å. O2- is bonded in a 1-coordinate geometry to two equivalent Ag1+ and one N3- atom.