Spin Density Distribution in Iron(II) and Cobalt(II) Alkyl Complexes Containing 1,3-Bis(2-pyridylimino)isoindolate Ligands
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https://figshare.com/articles/dataset/Spin_Density_Distribution_in_Iron_II_and_Cobalt_II_Alkyl_Complexes_Containing_1_3_Bis_2_pyridylimino_isoindolate_Ligands/2445496
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资源简介：
Iron(II) and cobalt(II) alkyl complexes using tridentate
bis(pyridylimino)isoindolates
as ancillary ligands have been synthesized from the pyridine alkyl
precursor complexes [(py)2Fe(CH2SiMe3)2] and [(py)2Co(CH2SiMe3)2]. The extremely air- and moisture-sensitive compounds
were structurally characterized in the solid state by X-ray diffraction
as well as in solution by paramagnetic NMR spectroscopy. It is demonstrated
that the paramagnetic shifts in the 13C NMR spectra are
dominated by strong Fermi-contact interactions. All 13C
NMR signals can be assigned by correlation with DFT-calculated spin-density
distributions.
创建时间：
2016-02-19
