Ferromagnetically Coupled Dimer of Cu<sup>II</sup>-Substituted γ-Decatungstosilicate
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A novel copper-substituted polyoxoanion [Cu4(H2O)2(OH)4Si2W16O58]8- (1) has been synthesized as its sodium salt, Na8-1·26H2O (Na-1), potassium salt, K8-1·28H2O(K-1), and calcium salt, Ca4-1·48H2O (Ca-1). Compound 1 is the first dimer of dicopper-substituted γ-decatungstosilicate fused in an unprecedented side-by-side dimerization mode with a ferromagnetic coupling property.
创建时间:
2016-06-03



