Toward Coordination Polymers Based on Fine-Tunable Group 13 Organometallic Phthalates
收藏NIAID Data Ecosystem2026-03-08 收录
下载链接：
https://figshare.com/articles/dataset/Toward_Coordination_Polymers_Based_on_Fine_Tunable_Group_13_Organometallic_Phthalates/2272453
下载链接
链接失效反馈官方服务：
资源简介：
A family of group 13 organometallic
macrocyclic phthalates [(MMe2)2(μ-O2C)2-1,2-C6H4]2 (where M = Al (1),
Ga (2), In (3)) is prepared, and the reactivity
of these homologous carboxylates toward various monodentate Lewis
bases is investigated. The studies provide the first structurally
characterized methylindium [{(Me2In)(μ-O2C)2-1,2-C6H4}{Me2In(THF)}]n (4) and methylaluminum [{(Me2Al)(μ-O2C)2-1,2-C6H4}{Me2Al(py-Me)}]n (5) 1D coordination polymers stabilized by dicarboxylate ligands
as a result of disruption of the parent tetranuclear macrocyclic structural
motifs in 3 and 1 by the incoming donor
ligands. The molecular and crystal structures of the reported compounds
are examined by spectroscopic studies and single-crystal X-ray diffraction.
创建时间：
2016-02-17
