Diastereoselective Construction of Trans-Fused Octalone Framework via Ruthenium-Porphyrin-Catalyzed Cycloaddition
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https://figshare.com/articles/dataset/Diastereoselective_Construction_of_i_Trans_i_Fused_Octalone_Framework_via_Ruthenium_Porphyrin_Catalyzed_Cycloaddition/2292010
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Lewis acid catalyzed cycloaddition of cyclohexenone and butadiene affords trans-fused octalone with high regio- and diastereoselectivity. The use of the ruthenium porphyrin complex as the Lewis acid catalyst is key to the reaction. The cycloaddition proceeds in toluene with 1 mol % of the ruthenium catalyst at 25 °C.
创建时间：
2016-02-17
