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Oxidative Carbon−Carbon Bond Formation via Silyl Bis-enol Ethers: Controlled Cross-Coupling for the Synthesis of Quaternary Centers

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NIAID Data Ecosystem2026-03-06 收录
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Unsymmetrical silyl bis-enol ethers have been developed as effective substrates for synthesizing quaternary centers from tetralone derivatives through oxidative carbon−carbon bond formation. The derived products are shown to be highly versatile intermediates that may be used to generate diverse structures such as cyclopentenones, 2H-pyrroles, and spirocyclic pyrrolidines.

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2016-06-03
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