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Emissive Chromium(III) Complexes with Substituted Arylethynyl Ligands

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https://figshare.com/articles/dataset/Emissive_Chromium_III_Complexes_with_Substituted_Arylethynyl_Ligands/2892793
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Arylethynylchromium(III) complexes of the form trans-[Cr(cyclam)(CCC6H4R)2]OTf (where cyclam = 1,4,8,11-tetraazacyclotetradecane, R = H, CH3, or CF3 in the para position, and OTf = trifluoromethanesulfonate) have been prepared and characterized by IR spectroscopy and X-ray diffraction. The complexes are emissive with excited-state lifetimes in a deoxygenated fluid solution between 200 and 300 μs.
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2008-12-15
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