Synthesis and Structural Characterization of Bi- and Trimetallic Octacyanometalate(IV) Complexes: [Δ,Λ-M<sup>II</sup>(en)<sub>3</sub>][<i>cis</i>-M<sup>II</sup>(en)<sub>2</sub>(OH<sub>2</sub>)][M<sup>IV</sup>(CN)<sub>8</sub>]·2H<sub>2</sub>O and [<i>cis</i>-M<sup>II</sup>(en)<sub>2</sub>(OH<sub>2</sub>)]<sub>2</sub>[(μ-NC)<sub>2</sub>M<sup>IV</sup>(CN)<sub>6</sub>]·4H<sub>2</sub>O (M<sup>II</sup> = Mn, Co, Ni; M<sup>IV</sup> = Mo, W)
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数据链接：
https://figshare.com/articles/dataset/Synthesis_and_Structural_Characterization_of_Bi_and_Trimetallic_Octacyanometalate_IV_Complexes__M_sup_II_sup_en_sub_3_sub_i_cis_i_M_sup_II_sup_en_sub_2_sub_OH_sub_2_sub_M_sup_IV_sup_CN_sub_8_sub_2H_sub_2_sub_O_and_i_cis_i_M_sup_II_sup_en_sub_2_sub_OH_sub_/3303586数据链接链接失效反馈
官方服务：
资源简介：
Treatment of [MII(en)3][OTs]2 or methanolic ethylenediamine solutions containing transition metal p-toluenesulfonates (MII = Mn, Co) with aqueous K4MIV(CN)8·2H2O or Cs3MV(CN)8 (MIV = Mo, W; MV = Mo) affords crystalline clusters of [MII(en)3][cis-MII(en)2(OH2)(μ-NC)MIV(CN)7]·2H2O (MIV = Mo; MII = Mn, 1; Ni, 5; MIV = W; MII = Mn, 2; Ni, 6) and [cis-MII(en)2(OH2)]2[(μ-NC)2MIV(CN)6]·4H2O (MIV = Mo; MII = Co, 3; Ni, 7; MIV = W; MII = Co, 4) stoichiometry. Each cluster contains cis-MII(en)2(OH2)(μ-NC)2+ units that likely result from dissociative loss of en from [MII(en)3]2+, affording cis-MII(en)2(OH2)22+ intermediates that are trapped by MIV(CN)84-.
创建时间：
2016-05-06
