Tandem Ruthenium-Catalyzed Transfer-Hydrogenative Cyclization/Intramolecular Diels–Alder Reaction of Enediynes Affording Dihydrocoumarin-Fused Polycycles
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https://figshare.com/articles/dataset/Tandem_Ruthenium_Catalyzed_Transfer_Hydrogenative_Cyclization_Intramolecular_Diels_Alder_Reaction_of_Enediynes_Affording_Dihydrocoumarin_Fused_Polycycles/2313220
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资源简介:
A tandem
transfer-hydrogenative cyclization/intramolecular Diels–Alder
reaction of enediyne substrates, containing 1,6-diyne, acrylate dienophile,
and phenol tether moieties, was successfully accomplished using the
combination of a cationic ruthenium complex, [CpRu(AN)3]PF6 (1b, Cp = η5-C5H5, AN = MeCN), as the catalyst and a Hantzsch
ester as the H2 surrogate to afford interesting dihydrocoumarin-fused
polycyclic products as single diastereomers.
创建时间:
2016-02-17



