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Tandem Ruthenium-Catalyzed Transfer-Hydrogenative Cyclization/Intramolecular Diels–Alder Reaction of Enediynes Affording Dihydrocoumarin-Fused Polycycles

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NIAID Data Ecosystem2026-03-08 收录
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https://figshare.com/articles/dataset/Tandem_Ruthenium_Catalyzed_Transfer_Hydrogenative_Cyclization_Intramolecular_Diels_Alder_Reaction_of_Enediynes_Affording_Dihydrocoumarin_Fused_Polycycles/2313220
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资源简介:
A tandem transfer-hydrogenative cyclization/intramolecular Diels–Alder reaction of enediyne substrates, containing 1,6-diyne, acrylate dienophile, and phenol tether moieties, was successfully accomplished using the combination of a cationic ruthenium complex, [CpRu­(AN)3]­PF6 (1b, Cp = η5-C5H5, AN = MeCN), as the catalyst and a Hantzsch ester as the H2 surrogate to afford interesting dihydrocoumarin-fused polycyclic products as single diastereomers.
创建时间:
2016-02-17
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