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4,12-Bis(2,2-dibromovinyl)[2.2]paracyclophane

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Mendeley Data2024-03-27 更新2024-06-27 收录
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https://search-data.ubfc.fr/FR-18008901306731-2016-08-23-03_4-12-Bis-2-2-dibromo-vinyl-2-2-paracyclo-phane.html
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资源简介:
In the title compound, C20H16Br4, both vinylic substituents were introduced by a Corey-Fuchs reaction using 4,12-diformyl[2.2]paracyclophane as starting material. The title compound may be used as a valuable precursor for the synthesis of diethynyl[2.2]paracyclophane. The title molecule is centrosymmetric with a crystallographic center of inversion between the centers of the two phenyl rings. A strong tilting is observed with an interplanar angle between the best aromatic plane and the vinyl plane of 49.4 (5)°. No significant intermolecular interactions are found in the crystal.
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2023-06-28
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