Synthesis and Structural Studies of Gallium(III) and Iron(III) Hemicryptophane Complexes
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https://figshare.com/articles/dataset/Synthesis_and_Structural_Studies_of_Gallium_III_and_Iron_III_Hemicryptophane_Complexes/2080393
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资源简介：
New gallium(III) and iron(III) endohedral
complexes were obtained from a hemicryptophane ligand bearing suitable
binding sites for octahedral metal coordination. The solid-state structures
of the free host and of the complexes were determined by single-crystal
X-ray diffraction analysis. The metal ion is linked to the hydrazone
nitrogen and the phenolate oxygen atoms, yielding a distorted octahedral
geometry around the encapsulated metal. The two isomorphous structures
of the metal complexes reveal the exclusive formation of PΔ/MΛ
enantiomeric pairs.
创建时间：
2016-02-10
