About of Possibility of Existence of Zn(IV) Oxidation State in Heteroligand Complexes with Porphyrazine, <i>trans</i>-Di[benzo]porphyrazine, Phthalocyanine, and Oxo Ligands: Quantum-Chemical Review

Based on the quantum-chemical calculation using the Density Functional Theory (DFT) method, the existence possibility of zinc heteroligand complexes with porphyrazine and its analogs – <i>trans</i>-di[benzo]porphyrazine or phthalocyanine and oxo ligands with an oxidation state of <b>IV</b> which is unknown for this element, was shown. The data on the structural parameters and multiplicity of the ground state of these complexes were presented. <i>Comments on Inorganic Chemistry</i> Volume ……., Issue ……., Pages ………. (2020). <b>About of Possibility of Existence of Zn(IV) Oxidation State in Heteroligand Complexes with Porphyrazine, <i>trans</i>-Di[benzo]porphyrazine, Phthalocyanine and Oxo Ligands: Quantum-Chemical Review</b>. Oleg V. Mikhailov, Denis V. Chachkov