Gold-Catalyzed Post-Ugi Ipso-Cyclization with Switchable Diastereoselectivity
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https://figshare.com/articles/dataset/Gold-Catalyzed_Post-Ugi_Ipso-Cyclization_with_Switchable_Diastereoselectivity/6807098
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资源简介：
A gold-catalyzed
post-Ugi ipso-cyclization for the diastereoselective
synthesis of spirocyclic pyrrol-2-one-dienone system is described.
Tuning the catalytic system, solvent, and temperature allowed selectively
attaining two sets of diastereoisomers. The scope of the process has
been evaluated, and a putative mechanistic model was proposed.
创建时间：
2018-07-11
