CuCl-Induced Formation and Migration of Isoindazolyl Carbenoids
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https://figshare.com/articles/dataset/CuCl_Induced_Formation_and_Migration_of_Isoindazolyl_Carbenoids/3015874
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资源简介：
Two azo-ene-butadiyne conjugated systems undergo CuCl-mediated cyclization to afford isoindazolyl
carbenoids that could be trapped with 2,3-dimethyl-2-butene as [2 + 1] cycloaddition products. X-ray
structure analysis of the resultant cyclopropanes showed that formal migration to the distal carbenoid
isomer and subsequent trapping had occurred. The possible CuCl-induced cyclization/migration pathways
were explored using density functional theory, which indicated that the reaction most likely occurred via
coordination of CuCl to the distal alkyne bond.
创建时间：
2007-03-30
