Synthesis and Structural Characterization of a Novel Dipalladium Complex with an Unprecedented PdCN Bonding Motif
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https://figshare.com/articles/dataset/Synthesis_and_Structural_Characterization_of_a_Novel_Dipalladium_Complex_with_an_Unprecedented_PdCN_Bonding_Motif/3775794
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资源简介：
Removal of the chloride atom from Pd{C(NXy)CH3}(Cl)(But2bipy) initiates a series of reactions
that lead to the formation of the novel dipalladium
complex [Pd(But2bipy){η2-[Pd(But2bipy){N(Xy)C(CH3)C(CH3)NXy}]}][BF4]2. In this process, two imidoyl
groups undergo a C−C coupling reaction generating a
bis-imino ligand that coordinates to two palladium centers, one of which is bound to a C−N bond of the ligand
giving an unprecedented three-membered PdCN ring.
创建时间：
2016-08-26
