Cobalt(II) Complex of a Diazoalkane Radical Anion
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https://figshare.com/articles/dataset/Cobalt_II_Complex_of_a_Diazoalkane_Radical_Anion/2163127
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资源简介：
β-Diketiminate
cobalt(I) precursors react with diphenyldiazomethane to give a compound
that is shown by computational studies to be a diazoalkane radical
anion antiferromagnetically coupled to a high-spin cobalt(II) ion.
Thermolysis of this complex results in formal N–N cleavage
to give a cobalt(II) ketimide complex. Experimental evaluation of
the potential steps in the mechanism suggests that free azine is a
likely intermediate in this reaction.
创建时间：
2016-02-13
