Viologen-Based Rotaxanes from Dibenzo-30-crown-10
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https://figshare.com/articles/dataset/Viologen-Based_Rotaxanes_from_Dibenzo-30-crown-10/6429407
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资源简介:
Three [2]rotaxanes
(4, 7, and 12) and one [3]rotaxane
(8) were synthesized based on
the dibenzo-30-crown-10/viologen binding motif. To the best of our
knowledge, these are the first rotaxanes formed from dibenzo-30-crown-10
and viologens. The rotaxanes were all characterized by 1H NMR, 13C NMR, and HRMS. An X-ray crystal structure of
one of the [2]rotaxanes (7) was obtained. This work demonstrates
for the first time that dibenzo-30-crown-10 does form pseudorotaxane
complexes with viologens in solution.
创建时间:
2018-06-04



