Expeditious Metal-Free Access to Functionalized Polycyclic Acetals under Mild Aqueous Conditions
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https://figshare.com/articles/dataset/Expeditious_Metal_Free_Access_to_Functionalized_Polycyclic_Acetals_under_Mild_Aqueous_Conditions/2264362
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资源简介:
A facile
approach for the synthesis of furopyrans and bicyclic
bisacetals under mild aqueous conditions is described. This potentially
green, diversity oriented approach involves cascade Michael addition
and cycloacetalization of pyranones and 1,3-dicarbonyls. An interesting
switch in the product class was observed depending on the type of
pyranone employed. Products of type I and II obtained herein are an integral part of several bioactive natural
products and medicinally interesting compounds.
创建时间:
2016-02-17



