A Concise Total Synthesis of (−)-Maoecrystal Z
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https://figshare.com/articles/dataset/A_Concise_Total_Synthesis_of_Maoecrystal_Z/2610523
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资源简介:
The first total synthesis of (−)-maoecrystal Z is described. The key steps of the synthesis include a diastereoselective TiIII-mediated reductive epoxide coupling reaction and a diastereoselective SmII-mediated reductive cascade cyclization reaction. These transformations enabled the preparation of (−)-maoecrystal Z in only 12 steps from (−)-γ-cyclogeraniol.
创建时间:
2016-02-22



