A Concise Total Synthesis of (−)-Maoecrystal Z
收藏NIAID Data Ecosystem2026-03-07 收录
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The first total synthesis of (−)-maoecrystal Z is described. The key steps of the synthesis include a diastereoselective TiIII-mediated reductive epoxide coupling reaction and a diastereoselective SmII-mediated reductive cascade cyclization reaction. These transformations enabled the preparation of (−)-maoecrystal Z in only 12 steps from (−)-γ-cyclogeraniol.
创建时间：
2016-02-22
