遇见数据集

Novel Iridaboranes from the Reactions of Cp*<sub>2</sub>Ir<sub>2</sub>H<i><sub>x</sub></i>Cl<sub>4</sub><sub>-</sub><i><sub>x</sub></i>, <i>x</i> = 0−2, with LiBH<sub>4</sub>. Existence of a Concurrent Reaction Channel in the Conversion of Metal Chlorides to Metal Hydrides

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Reaction of either Cp*2Ir2Cl4 or Cp*2Ir2HCl3 with LiBH4 leads to formation of the new iridaborane Cp*Ir(H)2B3H7, 1 (a borallyl complex), in parallel with Cp*IrH4. In contrast, reaction of Cp*2Ir2H2Cl2 with LiBH4 leads exclusively to Cp*2Ir2(H)3B2H5, 3, which is isolobal with 1.

创建时间:
2016-08-27
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