Diastereoselective Construction of <i>Trans</i>-Fused Octalone Framework via Ruthenium-Porphyrin-Catalyzed Cycloaddition
收藏NIAID Data Ecosystem2026-03-08 收录
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资源简介：
Lewis acid catalyzed cycloaddition of cyclohexenone and butadiene affords trans-fused octalone with high regio- and diastereoselectivity. The use of the ruthenium porphyrin complex as the Lewis acid catalyst is key to the reaction. The cycloaddition proceeds in toluene with 1 mol % of the ruthenium catalyst at 25 °C.
创建时间：
2014-05-16
