Proximity Enforced Agostic Interactions Involving Closed-Shell Coinage Metal Ions
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https://figshare.com/articles/dataset/Proximity_Enforced_Agostic_Interactions_Involving_Closed-Shell_Coinage_Metal_Ions/10565594
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资源简介：
A proximity enforcing diarylsilane ligand is reported,
which gives
rise to unusual Si–H···M interactions with the
d10 metal ions Cu+ and Ag+ upon complexation.
These interactions are studied in detail both experimentally and computationally
and can be classified to be weakly agostic in nature for the Si–H···Cu
interaction. The Si–H···Ag interaction has more
signatures of an electrostatic contact.
创建时间：
2019-11-20
