Bimetallic Oxidative Addition in Nickel-Catalyzed Alkyl–Aryl Kumada Coupling Reactions
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https://figshare.com/articles/dataset/Bimetallic_Oxidative_Addition_in_Nickel_Catalyzed_Alkyl_Aryl_Kumada_Coupling_Reactions/2241745
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The mechanism of alkyl–aryl Kumada coupling catalyzed by the nickel pincer complex Nickamine was studied. Experiments using radical-probe substrates and DFT calculations established a bimetallic oxidative addition mechanism. Kinetic measurements showed that transmetalation rather than oxidative addition was the turnover-determining step. The transmetalation involved a bimetallic pathway.
创建时间：
2016-02-16
